The first examples of [3+2] cycloadditions with the participation of (E)‐3,3,3‐tribromo‐1‐nitroprop‐1‐ene / Karolina Zawadzińska, Zuzanna Gadocha, Kamila Pabian, Aneta Wróblewska, Ewelina ... więcej

The first examples of [3+2] cycloadditions with the participation of (E)‐3,3,3‐tribromo‐1‐nitroprop‐1‐ene / Karolina Zawadzińska, Zuzanna Gadocha, Kamila Pabian, Aneta Wróblewska, Ewelina Wielgus, Radomir Jasiński // Materials [Dokument elektroniczny]. – 2022, Vol. 15, Iss. 21, 9 s. : rys., tab. – Tryb dostępu: https://www.mdpi.com/1996-1944/15/21/7584. – Oznaczenie ref./art.: 7584. – Bibliogr. 39 poz., Abstr. – This article belongs to the Special Issue: Recent Advances in the Chemistry of Halogens. – doi: 10.3390/ma15217584. – ISSN 1996-1944

The first examples of [3+2] cycloaddition reactions between 3,3,3-tribromo-1-nitroprop-1-ene (TBMN) were explored on the basis of experimental and theoretical approaches. It was found that reactions involving ... więcej

The first examples of [3+2] cycloaddition reactions between 3,3,3-tribromo-1-nitroprop-1-ene (TBMN) were explored on the basis of experimental and theoretical approaches. It was found that reactions involving TBMN and diarylnitrones realized with full regio- and stereoselectivity lead to respective 3,4-cis-4,5-trans-4-nitroisoxazolidines. The regioselecticity and the molecular mechanism of title processes was analyzed on the basis of the advanced DFT computational study.