Development of carbazole and bipyridine copolymers as novel photovoltaic materials / Dariusz Bogdal, Michal Pajda, Jerzy Sanetra, Monika Pokladko, Katarzyna Matras, Andre-Jean Attias, Jean-Luis Fave // ... więcej

Development of carbazole and bipyridine copolymers as novel photovoltaic materials / Dariusz Bogdal, Michal Pajda, Jerzy Sanetra, Monika Pokladko, Katarzyna Matras, Andre-Jean Attias, Jean-Luis Fave // Macromolecular Symposia [Dokument elektroniczny]. – 2008, Vol. 268, Iss. 1, s. 110-114 : rys., tab., wykr. – Tryb dostępu: http://onlinelibrary.wiley.com/doi/10.1002/masy.200850823/pdf. – Bibliogr. 16 poz., Summ. – Mat. konf.: Advanced Polymer Materials for Photonics and Electronics : 47th Microsymposium, Prague, Czech Republic, 15-19.07.2007. – doi: 10.1002/masy.200850823. – ISSN 1521-3900

A novel acrylate polymer with a carbazole pendant group and bipyridine derivatives as side chains was synthesized, in which derivatives of bipyridine as electro-optic chromophores and carbazole as photoconductive ... więcej

A novel acrylate polymer with a carbazole pendant group and bipyridine derivatives as side chains was synthesized, in which derivatives of bipyridine as electro-optic chromophores and carbazole as photoconductive moiety were covalently linked to the acrylate backbone. 2–(Carbazol-9-yl)ethyl methacrylate (CEM) and methacrylic 2-[5-(2-{5,50 -dimethyl-60 -[2-(5-pentylthiophen-2-yl)vinyl]-3,30 -bipyridin-6yl}vinyl)thiophen-2-yl]ethyl methacrylate (BiPy) were synthesized and then copolymerized to give 99:1, 98:2, 92:8 (mol/mol) CEM/BiPy copolymers. Films of the copolymers blended with poly(3-octylthiophene) (P3OT) or poly(3-decylthiophene) (PDT) and sandwiched between the transparent ITO and Al electrode were examined for photovoltaic properties.