Solubility products and solubility concepts / Anna Maria Michałowska-Kaczmarczyk, Aneta Spórna-Kucab and Tadeusz Michałowski // W: Descriptive inorganic chemistry researches of metal compounds [Dokument ... więcej

Solubility products and solubility concepts / Anna Maria Michałowska-Kaczmarczyk, Aneta Spórna-Kucab and Tadeusz Michałowski // W: Descriptive inorganic chemistry researches of metal compounds [Dokument elektroniczny] / ed. by Takashiro Akitsu. – Rijeka : IntechOpen, 2017. – S. 93-134 : rys., tab., wykr. – Tryb dostępu: https://www.intechopen.com/books/descriptive-inorganic-chemistry-researches-of-metal-compounds. – Bibliogr. 97 poz., Abstr. – doi: 10.5772/67840. – ISBN 978-953-51-3398-8 (online). – ISBN 978-953-51-3397-1 (print). – ISBN 978-953-51-4696-4 (eBook PDF)

The chapter refers to a general concept of solubility product Ksp of sparingly soluble hydroxides and different salts and calculation of solubility of some hydroxides, oxides, and different salts in aqueous ... więcej

The chapter refers to a general concept of solubility product Ksp of sparingly soluble hydroxides and different salts and calculation of solubility of some hydroxides, oxides, and different salts in aqueous media. A (criticized) conventional approach, based on stoichiometry of a reaction notation and the solubility product of a precipitate, is compared with the unconventional/correct approach based on charge and concentration balances and a detailed physicochemical knowledge on the system considered, and calculations realized according to generalized approach to electrolytic systems (GATES) principles. An indisputable advantage of the latter approach is proved in simulation of static or dynamic, two-phase nonredox or redox systems.