Application of the molecular electron density theory to describe the reactivity of nitrile N-oxides and selectivity of their reactions with selected pi-deficient unsaturated components / Karolina Zawadzińska, ... więcej

Application of the molecular electron density theory to describe the reactivity of nitrile N-oxides and selectivity of their reactions with selected pi-deficient unsaturated components / Karolina Zawadzińska, Karolina Kula // W: National Scientific Conference “Understand the Science” V edition, September 25, 2021, National Scientific Conference “e-Factory of Science” VI edition, November 20, 2021 : The Book of Articles [Dokument elektroniczny] / ed. Norbert Kępczak, Paweł Solarczyk. – Łódź : Promovendi Foundation Publishing, 2021. – S. 57-62 : rys. – Tryb dostępu: https://promovendi.pl/wp-content/uploads/2021/12/The-Book-of-Articles-National-Scientific-Conferences-UtS-_-eFoS.pdf. – Bibliogr. 27 poz., Abstr. – ISBN 978-83-961157-8-2

Molecular Electron Density Theory (MEDT) is a new, powerful tool that could be used to predict the reactivity and mechanism of many organic reactions. In following paper the MEDT was used to describe the ... więcej

Molecular Electron Density Theory (MEDT) is a new, powerful tool that could be used to predict the reactivity and mechanism of many organic reactions. In following paper the MEDT was used to describe the nature of addents in [3+2] cycloaddition which provides five membered heterocycled compounds – isoxazoles and their analogs. The most popular group of dipoles in [3+2] cycloaddition – nitrile N-oxide was characterised. Reactivity and behaviour of nitrile N-oxides in the reactions with selected -deficite components was studied. Following paper provides an overview of the available literature.